May 12, 2011
Large Uranium Clusters on the cover of Angewandte Chemie

Nanosized oxide and hydroxide clusters of actinides (uranium, plutonium) play an important role in technology for the nuclear industry, in the migration of the actinides released in the environment by mining, energy production or weapons, and into related remediation strategies. Nanoparticle formation is likely to impact uranium mobility and limit the efficiency of microbial reduction in actinide immobilization.

The paper presents a reproducible method for the synthesis of such clusters from the stoichiometric hydrolysis of low-valent uranium in non-aqueous media. The cluster size can be tuned by the choice of solvent and organic base, leading for instance to a U16 compound that is the largest UIV cluster reported to date. These new clusters show unprecedented {U10O14} and {U16O24} topologies. These nanosized oxides provide useful models for understanding the chemistry of bulk oxides or colloids.

Biswas, B., Mougel, V., Pécaut, J. and Mazzanti, M. (2011), Base-Driven Assembly of Large Uranium Oxo/Hydroxo Clusters. Angewandte Chemie International Edition, 50: 5745–5748. doi: 10.1002/anie.201101327

 

Last update : 08/19 2011 (745)

 

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